Low-pressure solubilities and thermodynamics of solvation of eight gases in 1-butyl-3-methylimidazolium hexafluorophosphate
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چکیده
منابع مشابه
synthesis of 3-aryl-2h-benzo[b]-1,4-oxazines in [omim]bf4 and reduction of organic compounds in methylimidazolium formate
در این پروژه ترکیبات 3-آریل-2h-بنزو[b]-4،1-اکسازین ها از مواد اولیه تجاری مشتقات دو آمینو فنول و ?-هالو کتون های آروماتیک در مایع یونی 1-اکتیل-3-متیل ایمیدازولیوم تترا فلورو بورات([omim]bf4) سنتز شده است. این واکنش توسط باز پتاسیم کربنات محلول از طریق o-آلکیلاسیون و سپس یک واکنش آمیداسیون درون مولکولی خود بخود در مدت زمان کوتاه انجام می شود. ترکیبات 4،1-بنزوکسازین به این روش با بهره خوب تا آلی ...
15 صفحه اولUultra-trace determination of cadmium (II) in aqueous environmental samples by a new ion selective electrode based on nefazodone and 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid
Background and Objective: Cadmium is a potential environmental contaminant that causes adverse effects on the environment and the health of living organisms. Therefore, designing a simple and economic technique for its determination is very important. In this respect, a potentiometric sensor based on nefazodone as the ionophore and [BMIM]PF6 as the ionic additive were developed for the determin...
متن کاملTransport properties of binary mixtures of carbon dioxide and 1-butyl-3-methylimidazolium hexafluorophosphate studied by transient grating spectroscopy.
Transient grating spectroscopy was applied to measurements of sound velocity and thermal diffusivity in binary mixture solutions of carbon dioxide (CO(2)) and 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIm][PF(6)]) along the saturated line of CO(2) at 40 degrees C up to 20.0 MPa. The sound velocity decreased more than 10% by increasing the pressure to 10 MPa, and the pressure effect was...
متن کاملThermodynamics of cellulose solvation in water and the ionic liquid 1-butyl-3-methylimidazolim chloride.
Cellulose is present in biomass as crystalline microfibrils held together by a complex network of intermolecular interactions making it difficult to initiate its hydrolysis and conversion to fuels. While cellulose is insoluble in water and most organic solvents, complete dissolution of cellulose can be achieved in certain classes of ionic liquids (ILs). The present study was undertaken to analy...
متن کاملReduction of carbon dioxide in 1-butyl-3-methylimidazolium acetate.
Gaseous CO(2) is almost irreversibly absorbed by the room temperature ionic liquid 1-butyl-3-methylimidazolium acetate ([C(4)mim][Ac]) in which it undergoes a chemically irreversible, one electron electrochemical reduction, suggesting a means for the sequestration of the greenhouse gas.
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ژورنال
عنوان ژورنال: Fluid Phase Equilibria
سال: 2006
ISSN: 0378-3812
DOI: 10.1016/j.fluid.2005.12.003